V
Villiamza
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Defenders of Hatra in what is now modern day Iraq saw off an attack by a Roman army in AD 198 by launching clay jars stuffed with Death Stalker scorpions, "the Deathstalker is regarded as the most dangerous species of scorpion" (wikipedia??)
Source - Greek Fire, Poison Arrows and Scorpion Bombs: Biological Warfare in the Ancient World.
Source - Greek Fire, Poison Arrows and Scorpion Bombs: Biological Warfare in the Ancient World.